• 摘要: 针尖增强纳米光谱术(Tip-enhanced nanospectroscopy, TENS)是一种结合扫描探针显微镜与针尖纳米聚焦光源的高空间分辨率光谱表征技术。该方法能够在纳米乃至亚纳米尺度上同步获取样品表面形貌与化学结构信息,为物理、化学、材料科学、生物及纳米技术等多个前沿领域提供强有力的研究工具。首先概述了三种常用扫描探针显微镜的反馈原理;随后系统介绍了等离激元探针的类型、激发方式及其纳米聚焦特性;进一步详细讨论了多种典型TENS系统的构型与特点;最后综述了TENS在单分子成像、非线性光谱、相干反斯托克斯拉曼散射、荧光增强及暗态拉曼可视化等重要领域中的应用与前沿进展。

       

      Abstract: Tip-enhanced nanospectroscopy (TENS) is a high-spatial-resolution spectroscopic technique that integrates scanning probe microscopy (SPM) with nanofocusing light sources at the tip apex. This method enables the simultaneous acquisition of surface topography and chemical structural information at the nanometric and even sub-nanometric scale, providing a powerful tool for research in physics, chemistry, materials science, biology, and nanotechnology. This article begins with a brief introduction to the feedback mechanisms of three commonly used SPMs. It then systematically reviews the types of plasmonic tips, their excitation schemes, and nanofocusing characteristics. Furthermore, several typical configurations of TENS systems are discussed in detail. Finally, an overview is presented of the applications and recent advances of TENS in areas such as single-molecule imaging, nonlinear spectroscopy, coherent anti-Stokes Raman scattering, fluorescence enhancement, and dark-state Raman visualization.