Luminescence regulation of Sb<sup>3+</sup> in 0D hybrid metal halides by hydrogen bond network for optical anti-counterfeiting

Dehai Liang; Saif M. H. Qaid; Xin Yang; Shuangyi Zhao; Binbin Luo; Wensi Cai; Qingkai Qian; Zhigang Zang

doi:10.29026/oea.2024.230197

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Liang DH, Qaid SMH, Yang X et al. Luminescence regulation of Sb3+ in 0D hybrid metal halides by hydrogen bond network for optical anti-counterfeiting. Opto-Electron Adv 7, 230197 (2024). doi: 10.29026/oea.2024.230197

Citation:

Liang DH, Qaid SMH, Yang X et al. Luminescence regulation of Sb³⁺ in 0D hybrid metal halides by hydrogen bond network for optical anti-counterfeiting. Opto-Electron Adv 7, 230197 (2024). doi: 10.29026/oea.2024.230197

Article Open Access

Luminescence regulation of Sb³⁺ in 0D hybrid metal halides by hydrogen bond network for optical anti-counterfeiting

1.
Key Laboratory of Optoelectronic Technology & Systems (Ministry of Education), Chongqing University, Chongqing 400044, China
2.
Department of Physics & Astronomy, College of Sciences, King Saud University, P.O. Box 2455, Riyadh 11451, Saudi Arabia
3.
Department of Chemistry and Chemical Engineering, Key Laboratory for Preparation and Application of Ordered Structural Materials of Guangdong Province, Shantou University, Shantou 515063, China
4.
Department of Oil, Army Logistics Academy of PLA, Chongqing 401311, China

More Information

^*Corresponding authors: X Yang, E-mail: beyondyzs@126.com; SY Zhao, E-mail: shyzhao@cqu.edu.cn; BB Luo, E-mail: bbluo@stu.edu.cn; ZG Zang, E-mail: zangzg@cqu.edu.cn

Received Date 27 October 2023

Accepted Date 05 January 2024

Available Online 13 March 2024

Published Date 22 March 2024

Abstract

Abstract

The Sb³⁺ doping strategy has been proven to be an effective way to regulate the band gap and improve the photophysical properties of organic-inorganic hybrid metal halides (OIHMHs). However, the emission of Sb³⁺ ions in OIHMHs is primarily confined to the low energy region, resulting in yellow or red emissions. To date, there are few reports about green emission of Sb³⁺-doped OIHMHs. Here, we present a novel approach for regulating the luminescence of Sb³⁺ ions in 0D C₁₀H₂₂N₆InCl₇·H₂O via hydrogen bond network, in which water molecules act as agents for hydrogen bonding. Sb³⁺-doped C₁₀H₂₂N₆InCl₇·H₂O shows a broadband green emission peaking at 540 nm and a high photoluminescence quantum yield (PLQY) of 80%. It is found that the intense green emission stems from the radiative recombination of the self-trapped excitons (STEs). Upon removal of water molecules with heat, C₁₀H₂₂N₆In_1-xSb_xCl₇ generates yellow emission, attributed to the breaking of the hydrogen bond network and large structural distortions of excited state. Once water molecules are adsorbed by C₁₀H₂₂N₆In_1-xSb_xCl₇, it can subsequently emit green light. This water-induced reversible emission switching is successfully used for optical security and information encryption. Our findings expand the understanding of how the local coordination structure influences the photophysical mechanism in Sb³⁺-doped metal halides and provide a novel method to control the STEs emission.
- indium-based halides /
- Sb³⁺ doping /
- hydrogen bonding network /
- optical anti-counterfeiting

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References

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