激光制备超疏水表面研究进展

杨焕, 曹宇, 李峰平, 等. 激光制备超疏水表面研究进展[J]. 光电工程, 2017, 44(12): 1160-1168. doi: 10.3969/j.issn.1003-501X.2017.12.003
引用本文: 杨焕, 曹宇, 李峰平, 等. 激光制备超疏水表面研究进展[J]. 光电工程, 2017, 44(12): 1160-1168. doi: 10.3969/j.issn.1003-501X.2017.12.003
Huan Yang, Yu Cao, Fengping Li, et al. Research progress in superhydrophobic surfaces fabricated by laser[J]. Opto-Electronic Engineering, 2017, 44(12): 1160-1168. doi: 10.3969/j.issn.1003-501X.2017.12.003
Citation: Huan Yang, Yu Cao, Fengping Li, et al. Research progress in superhydrophobic surfaces fabricated by laser[J]. Opto-Electronic Engineering, 2017, 44(12): 1160-1168. doi: 10.3969/j.issn.1003-501X.2017.12.003

激光制备超疏水表面研究进展

  • 基金项目:
    国家自然科学基金(51375348,U1609209);浙江省杰出青年基金项目(LR15E05003);温州激光与光电企业集群重点专项(J20150003)
详细信息
    通讯作者: 李峰平, E-mail: wzulfp@126.com
  • 中图分类号: O647.1

Research progress in superhydrophobic surfaces fabricated by laser

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  • 由于超疏水表面在防腐、油水分离、流体减阻和液体转移方面的应用潜力,如何制作性能优异的超疏水表面成为研究热点。材料表面的形貌特征是决定其润湿性能的一个重要因素,因此,通常采用表面结构化来获得超疏水性能。在材料表面构织微纳结构方面,基于脉冲激光的微纳加工技术具有得天独厚的优势,尤其是在制作特定图案的复杂结构方面。本文根据激光器的脉冲宽度分类,通过刻蚀后材料表面形貌和润湿性特征对激光制作超疏水表面的基本理论和典型工艺方法进行介绍和总结,并对超疏水表面的发展前景作出展望。

  • Abstract: Superhydrophobic surfaces, which are defined by the water contact angle higher than 150° and the slide angle lower than 10°, have recently attracted more and more attention due to their important applications in anti-corrosion, oil-water separation, friction reduction, and liquid transportation. Over the past few decades, many methods have been developed to fabricate superhydrophobic surfaces which can usually be achieved by creating a rough surface structure on a hydrophobic material or depositing a layer of chemical molecules with low surface energy onto a rough surface, so surface morphology is a key factor to determine the wettability of a solid surface, and patterning is one of the effective ways to change the surface morphology and to improve the wetting properties. Laser patterning using a pulse laser source is a unique technique that can modify the surface morphology with very limited distortion of the bulk material. Moreover, it is a noncontact method, and complex patterns can be created. The basic wettability theory of solid surface was introduced, such as Young equation, Wenzel model, Cassie-Baxter model, wetting courses and conditions. As the surperhydrophobicity depends on the surface microstructure of materials, and the pulse width is one of the key factors affecting the processing accuracy and quality of laser fabricated microstructure, the research progress in the superhydrophobic surfaces fabricated by laser was classified based on the laser pulse width (nanosecond, picosecond and femtosecond). Several typical approaches of laser fabricated superhydrophobic surfaces were summarized, including the laser texturing and subsequent surface modified technologies, meanwhile the surface morphologies and wetting properties of the surperhydrophobic surfaces fabricated with different laser pulse width were compared, and the relevant applications were also presented. The cost of nanosecond laser is relatively low, but the processing accuracy is restricted by the diffraction theory, and the nanosecond laser is not suitable for fabricating superhydrophobic surface on hard-brittle transparent materials, so as on low-melting materials. The nonlinear absorption effect of femtosecond laser could obtain the processing accuracy which is much smaller than the focal spot, meanwhile depending on this effect, microstructure superhydrophobic surfaces could be fabricated on almost all the solid materials. Although the research in the field of superhydrophobic surfaces has been conducted for over ten years, the fabricating cost and durability still could not meet the requirements of industrial application.

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  • 图 1  接触角的定义[28].

    Figure 1.  Definition of contact angle[28].

    图 2  水滴与粗糙结构不同的接触状态. (a) Wenzel状态[30]. (b) Cassie-Baxter状态[31].

    Figure 2.  Schematic diagram of superhydrophobic state. (a) Wenzel state[30]. (b) Cassie-Baxter state[31].

    图 3  (a) 纳秒激光在钨表面制备微纳结构[36]. (b)纳秒激光在不锈钢表面制备的超疏水结构[37]. (c)纳秒紫外激光在金属表面制备微纳米复合结构[38]. (d)红外纳秒激光在纯铜表面制作超疏水结构[39].

    Figure 3.  (a) Micro-nano structures fabricated on tungsten by nanosecond laser[36]. (b) Superhydrophobic structure fabricated on SUS by nanosecond laser[37]. (c) Micro-nano structures fabricated on metal by UV nanosecond laser[38]. (d) Superhydrophobic structure fabricated on copper by IR nanosecond laser[39].

    图 4  (a) 皮秒激光作用于不锈钢表面显微形貌[40]. (b)皮秒激光作用于钛合金表面显微形貌[40]. (c)皮秒激光作用于铝合金表面显微形貌[41].

    Figure 4.  (a) Micro-nano structures fabricated on SUS by picosecond laser[40]. (b) Micro-nano structures fabricated on titanium metal by picosecond laser[40]. (c) Micro-nano structures fabricated on aluminium metal by picosecond laser[41].

    图 5  激光制造磨具钢压印模板及压印铝合金和硅橡胶表面形貌[42]. (a)皮秒激光加工磨具钢后SEM图片. (b)皮秒激光加工磨具钢后单个凹坑显微结构. (c)铝合金压铸后表面凸起结构. (d)铝合金压铸后单个凸起显微. (e)硅橡胶表面凸起结构. (f)单个凸起高倍显微结构.

    Figure 5.  Surface morphologies of mold surface fabricated by laser and imprinted silicone rubber surfaces[42]. (a) SEM picture of die steel ablated by picosecond. (b) SEM picture of the single concave. (c) Aluminium alloy fabricated by casting. (d) SEM picture of the single convex on the aluminum alloy. (e) Silicone rubber fabricated by casting. (f) SEM picture of the single convex on the silicone rubber.

    图 6  激光刻蚀氧化铝陶瓷表面形貌[43]. (a)微沟槽结构. (b)微孔洞状结构.

    Figure 6.  SEM pictures[43]. (a) Micropillars. (b) Microholes on alumina ceramics.

    图 7  飞秒激光制备超疏水硅表面[47]. (a)超疏水表面宏观照片. (b)接触角测试图片. (c)激光烧蚀后硅表面SEM显微结构. (d)单个凸起结构高倍显微图片.

    Figure 7.  Micro-nano structures fabricated on silicon by femtosecond laser[47]. (a) Macrograph. (b) Contact angle. (c) Micro-nano structures fabricated on silicon. (d) SEM picture of the single convex.

    图 8  PDMS微纳米周期性结构[48].

    Figure 8.  Micro-nano structures on PDMS[48].

    图 9  飞秒激光在不锈钢表面制备超疏水表面微观结构[49]. (a)激光能量密度和扫描速度对材料表面结构的影响. (b)激光能量密度为77.1 J/cm2时表面形貌及超疏水性能. (c)激光能量密度为184 J/cm2时表面形貌及超疏水性能.

    Figure 9.  Micro-nano structures fabricated on SUS by femtosecond laser[49]. (a) Effect of the fluence and scanning speed on micro-nano structure. (b) Superhydrophobic surface at the fluence of 77.1 J/cm2. (c) Superhydrophobic surface at the fluence of 184 J/cm2.

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收稿日期:  2017-08-04
修回日期:  2017-11-06
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